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1. When a reaction is in dynamic equilibrium the rate of the forward reaction is the rate of the reverse reaction.

2. When a reaction is in dynamic equilibrium the concentrations of the reactants and products are always ...

  • A.   equal
  • B.   unequal with the reactant concentration greater than the product concentration
  • C.   unequal with the product concentration greater than the reactant concentration
  • D.   constant
3. The reaction of anhydrous copper(II)sulfate with water is an example of a reversible reaction: copper sulfate - blue and white
CuSO4 (s) + 5H2O (l)    ⇌   CuSO4.5H2O (s)
white       blue

If the reaction moves in the forward direction you will observe ...

  • A.   solid turning from white to blue
  • B.   solid dissolving
  • C.   solid turning from blue to white
  • D.   condensation forming on the sides of the test tube

Q4-5
The production of ammonia in the Haber Process is an example of a reversible reaction:

N2 (g) + 3H2 (g)   ⇌  2NH3 (g)  ΔH = - 92.4kJ

 

Select the answer which states and gives a reason for the effect on the yield of ammonia (NH3) of …

4. ...increasing the temperature:

  Yield of Ammonia Reason
A increases because the forward reaction is endothermic
B increases because the reverse reaction is endothermic
C decreases because the forward reaction is endothermic
D decreases because the reverse reaction is endothermic

5. ...increasing the pressure:

  Yield of Ammonia Reason
A increases because there are less moles of gas on the ‘products’ side
B increases because there are less moles of gas on the ‘reactants’ side
C decreases because there are less moles of gas on the ‘products’ side
D decreases because there are less moles of gas on the ‘reactants’ side
6. The decomposition of dinitrogen tetroxide is an endothermic process as bonds are broken.

This is also a reversible reaction and the equation for this reaction is:

N2O4 (g)      ⇌   2NO2 (g)   

What would be the effect on the position of equilibrium of increasing the temperature and of increasing the pressure?

Dinitrogen tetroxide
  Increasing the temperature Increasing the pressure
A Moves to the left Moves to the left
B Moves to the left Moves to the right
C Moves to the right Moves to the left
D Moves to the right Moves to the right
7. Hydrogen and chlorine react in a reversible reaction to produce hydrogen chloride:
H2(g) + Cl2(g)   ⇌   2HCl(g)
If the pressure is increased on this equilibrium system, what will happen to the equilibrium position?

8. To achieve a high yield (of SO3), what conditions of temperature and pressure would be required?

2SO2  + O2   ⇌  2SO3      ΔH = -385 kJ
 
  Temperature Pressure
A low low
B low high
C high low
D high high

Q9-10:
Hydrogen is produced in industry by reacting methane with steam at 2 atm pressure and 1000 °C. The equation for the reaction is:

CH4 (g) + H2O (g) CO (g) + 3H2 (g) ΔH= +210 kJ

What is the effect on the concentrations of carbon monoxide and hydrogen in the equilibrium mixture of carrying out the reaction at...

 

9. ...500oC?

  Carbon Monoxide Concentration Hydrogen Concentration
A increases decreases
B increases increases
C decreases decreases
D decreases increases

10. ...10atm?

  Carbon Monoxide Concentration Hydrogen Concentration
A increases decreases
B increases increases
C decreases decreases
D decreases increases
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Question 1:

The correct answer is equal to.

Explanation:
In a dynamic equilibrium, the rate of the forward reaction is equal to the rate of the reverse reaction.

This does not mean the concentrations of reactants and products are equal—rather, they are constant because the two reactions are occurring at the same rate in opposite directions. The system appears static at the macroscopic level, but at the molecular level, both reactions continue to happen simultaneously (hence "dynamic").


So the completed sentence is:
"When a reaction is in dynamic equilibrium the rate of the forward reaction is equal to the rate of the reverse reaction."


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Question 2:

The correct answer is D. constant.

Explanation:
In a dynamic equilibrium, the concentrations of reactants and products are constant (they do not change over time). This is because the forward and reverse reactions are occurring at the same rate, so any molecules of reactants that are converted into products are balanced by an equal number of product molecules converting back into reactants.

However, constant does NOT mean equal. The actual concentrations of reactants and products at equilibrium depend on the equilibrium position (which is determined by the equilibrium constant, Kc, and the reaction conditions). They could be equal in a rare case, but in general, they are not—they simply remain steady.


Here is why the other options are incorrect:


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Question 3:

The correct answer is A. solid turning from white to blue.

Explanation:
The equation shows:

If the reaction moves in the forward direction (left to right), anhydrous copper(II) sulfate reacts with water to form hydrated copper(II) sulfate. Therefore, you would observe the white solid turning blue.


Here is why the other options are incorrect:


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 4:

The correct answer is D. decreases because the reverse reaction is endothermic.

Explanation:
The forward reaction (N₂ + 3H₂ → 2NH₃) is exothermic (ΔH = -92.4 kJ, meaning heat is released).
Therefore, the reverse reaction (2NH₃ → N₂ + 3H₂) is endothermic (absorbs heat).

According to Le Chatelier's principle, if you increase the temperature, the system will shift to oppose the change by favouring the endothermic direction (the reverse reaction), because that absorbs the excess heat. This means the equilibrium shifts to the left, converting ammonia back into nitrogen and hydrogen, which decreases the yield of ammonia.


Here is why the other options are incorrect:


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 5:

The correct answer is A. increases because there are less moles of gas on the ‘products’ side.

Explanation:
For the Haber process:

According to Le Chatelier's principle, increasing the pressure favours the side of the reaction with fewer moles of gas (because this reduces the overall pressure). Since the products side has fewer moles of gas (2 moles vs 4 moles), the equilibrium shifts to the right (forward direction), which increases the yield of ammonia.


Here is why the other options are incorrect:


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 6:

Explanation:

  1. Increasing the temperature:
    The reaction is endothermic in the forward direction (bonds are broken to form NO₂). According to Le Chatelier's principle, increasing the temperature favors the endothermic direction to absorb the added heat. Therefore, the equilibrium moves to the right (toward more NO₂).

  2. Increasing the pressure:
    The reaction involves a change in the number of gas moles:

    • Left side: 1 mole of gas (N₂O₄)

    • Right side: 2 moles of gas (NO₂)
      Increasing the pressure favors the side with fewer gas moles to reduce the pressure. Thus, the equilibrium moves to the left (toward N₂O₄).

So, the effect is: Moves to the right for temperature, Moves to the left for pressure.

Answer: C


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 7:

For this reaction:

H₂(g) + Cl₂(g) ⇌ 2HCl(g)

If the pressure is increased, the equilibrium position will not change (it will remain constant).

Explanation:

Final answer: The equilibrium position does not move (remains constant).


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 8:

The correct answer is B: low temperature and high pressure.

Explanation:

  1. Temperature (Low):
    The reaction has a negative ΔH (-385 kJ), meaning the forward reaction (producing SO₃) is exothermic. According to Le Chatelier's principle, lowering the temperature favors the exothermic direction to release heat. Therefore, a low temperature shifts the equilibrium to the right, increasing the yield of SO₃.

  2. Pressure (High):
    Count the moles of gas on each side:

    • Left side (reactants): 2 moles of SO₂ + 1 mole of O₂ = 3 moles of gas.

    • Right side (products): 2 moles of SO₃ = 2 moles of gas.
      Increasing the pressure favors the side with fewer gas moles to reduce the pressure. Since the right side has 2 moles compared to 3 on the left, high pressure shifts the equilibrium to the right, increasing the yield of SO₃.

So, to achieve a high yield of SO₃, you would use low temperature and high pressure.

Answer: B


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 9:

Answer: C
Both the carbon monoxide concentration and hydrogen concentration decrease.

Reason:
The forward reaction is endothermic (+210 kJ). Lowering the temperature from 1000 °C to 500 °C favors the exothermic reverse reaction, shifting equilibrium to the left. This consumes CO and H₂, so their concentrations both decrease.


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 10:

The correct answer is C: decreases (for both Carbon Monoxide and Hydrogen).

Reason:
Count the moles of gas on each side:

Increasing the pressure favors the side with fewer gas moles to reduce the pressure. That is the left (reactant) side.

So the equilibrium shifts to the left, consuming CO and H₂. Therefore, both concentrations decrease.

Answer: C


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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